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Co(III) catalysed asymmetric ring-opening of epichlorohydrin by salicylaldehyde derivatives: reversal of enantioselectivity and rate acceleration on addition of AlCl3
Asymmetric catalysis salicylaldehyde Co(III) salen aryloxy alcohols epoxide ring-opening
2010/10/31
Using asymmetric Cobalt(III) salen catalysts, the ring-opening of epichlorohydrin by 2,3-dihydroxybenzal- dehyde and 2,4- dihydroxybenzaldehyde was found to occur at the phenolic groups most distant f...
Co(III) Catalysed Asymmetric Ring-Opening of Epichlorohydrin by Salicylaldehyde Derivatives: Reversal of Enantioselectivity and Rate Acceleration on Addition of AlCl3
Asymmetric catalysis salicylaldehyde Co(III) salen
2010/10/31
Using asymmetric Cobalt(III) salen catalysts, the ring-opening of epichlorohydrin by 2,3-dihydroxybenzaldehyde and 2,4- dihydroxybenzaldehyde was found to occur at the phenolic groups most distant fro...
Behaviour of Salicylaldehyde and Some of Its Derivatives in the Biginelli Reaction for the Preparation of Aryl Tetrahydropyrimidines
Salicylaldehyde derivatives Biginelli reaction Michael addition
2008/6/30
Salicylaldehyde and some of its derivatives react with urea (or thiourea) and ethyl acetoacetate (the Biginelli reaction) to give products that depend on the type of the substituent in the ortho-posit...