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The coordination environment of 20-200 ppm Pt in yellowish glasses from the CaO-Al O -SiO 2 3 2(CAS) ternary was studied using X-ray absorption fine structure spectroscopy at the Pt-L edge. IIIedge...
Abstract: Experiments on zeolitization were conducted on four synthetic monocationic glasses (Na, K, Ca, or Mg-rich glass) with Si/Al molar ratios of 2.67, similar in acidity to many volcanic glasses ...
The structure of sodium tetrasilicate (Na2Si4O9) glasses containing 0 to 10 wt% water was investigated by a combination of Raman, IR, and NMR methods. Both the 29 Si magic angle spinning NMR data and...
The effect of water (5 H2O 1 OH) on the environment of Co21and Ni21 in albite glass was investigated by electronic absorption spectroscopy. The visible spectra of Co21-doped glasses change only slight...
Thestateoforderingamongnetwork-modi?ercationsinmoltensilicateshasapoten-tiallylargeeffectontheiroverallcon?gurationalentropy,onfreeenergiesofmixing,and onviscosityanddiffusivity.Mostmodelsofthermodyn...
The coordination environment of Ti in eight Ti-bearing glasses of the Na Si-Na,Ti y4 ;:join (NTS) and in six ATY2 glasses (A20Ti02.2Y02, with A =Na, K, ~r Rb andSi or Ge) was determined using high-re...
In situ, high-temperature Raman spectroscopy of Na,O.9SiO, glasses and melts with and without 2 mol% P,05 has been conducted to 1491 K (near the liquidus temperature). In the temperature range from 29...
The time-dependent loss of NaKa X-ray intensity during electron-beam irradiation of hydrous alkali alumino silicate glasses is apparently moresignificant during the initial few seconds ofbeam exposure...
Wehave measured the pressures of decrepitation of vesicles in synthetic glasses of feldspar compositions (NaAlSi30g-KAlSi30g). Vesicles filled withXedo not decrepitate at internal pressures of 160 MPa...
Thermodynamic and transport properties often compositions in the binary system NaAISi04-Si02have beendetermined bythe methodofmoleculardynamics simulation. Thecomputations wereperformed oncollections...
Raman spectra ofNa2Si20sglassand Na2Si20sliquid have been collected in situ to pressuresof16GPaat300Kand 10GPaat885K.Inglasscompressed at300K,bands associated withintertetrahedral bridging 0 atoms de...
Assignmentofthe peaksnear485em-I in vibrational spectra ofSi02-M7;:;Al02(where M=an alkali oralkaline earth element) glassesto v,(T-O-T) modesin four-membered rings wastested withmolecularorbital cal...
Si K- and L-edge X-ray absorption near-edge structure (XANES) of SiOz-PzOs and NazO-SiOz-PzOs glasses containing PzOsabove 30mol%wereinvestigated using synchro-tron radiation. BothSiK-and L-edge spect...
High-resolution transmission electron microscopy (HRTEM) has shown regions of crystallites within noncrystalline matrices of three types of glass (volcanic glass, alkalic igneous glass, and synthetic,...

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